1450618-18-4

Basic information

• Product Name: (Z)-N,N-diethyl-3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hept-5-enofuranosiduronamide
• CAS NO: 1450618-18-4
• Molecular Weight: 375.465
• Mol File: 1450618-18-4.mol

Chemical Properties

• CAS DataBase Reference: (Z)-N,N-diethyl-3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hept-5-enofuranosiduronamide(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-N,N-diethyl-3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hept-5-enofuranosiduronamide(1450618-18-4)
• EPA Substance Registry System: (Z)-N,N-diethyl-3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hept-5-enofuranosiduronamide(1450618-18-4)

Safety Data

• Hazardous Substances Data: 1450618-18-4(Hazardous Substances Data)

Upstream product

• 104584-00-1 dimethyl (2-(diethylamino)-2-oxoethyl)phosphonate 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 2430-01-5 2-bromo-N,N-diethylacetamide 

Downstream Products

• 1450618-35-5 2-chloro-N,N-diethyl-3-[(4R)-3-O-benzyl-1,2-O-isopropylidene-β-L-threofuran-4-yl]cyclopropanecarboxamide 

Relevant articles and documents

Synthesis of highly functionalized enantiopure halocyclopropanes derived from carbohydrates

A chromium-mediated synthesis of enantiopure sugar-based halocyclopropanecarboxamides is reported. This reaction can be stereospecifically carried out on (E)- or (Z)-α,β-unsaturated amides and takes place with the formation of a new C-Hal stereogenic center, which is generated with total stereoselectivity. Synthetic applications of the obtained halocyclopropanecarboxamides are also reported. The structure of the halocyclopropanes and derivatives were established by X-ray analysis. A mechanism to explain these transformations is proposed. Copyright