145073-41-2Relevant academic research and scientific papers
Microwave assisted synthesis of triazolobenzoxazepine and triazolobenzoxazocine heterocycles
Ellison, Aubrey,Boyer, Robert,Hoogestraat, Paul,Bell, Michael
, p. 6005 - 6007 (2013)
Intramolecular click chemistry was utilized to effect synthesis of the benzofused, triazole ring systems. The trimethylsilyl group was found to impede the reaction progress, and therefore, conditions employing in situ removal of the TMS group coupled with
Rhodium-catalyzed asymmetric synthesis of β-branched esters from allylic amines
Laffoon, Summer D.,Wu, Zhao,Hull, Kami L.
supporting information, p. 7814 - 7817 (2018/07/25)
Allylic amines are converted to chiral, β-branched esters under rhodium catalysis in the presence of alcohol nucleophiles. Allylic amines with aliphatic and aromatic vinylic substituents are converted to ester products with excellent enantioselectivities in all cases. Several alcohol nucleophiles have been utilized in the reaction including 1° and 2° derivatives.
