145075-36-1

Basic information

• Product Name: 4(4-methoxyphenyl)(2-methylbutyl)sulfane
• Synonyms: 4(4-methoxyphenyl)(2-methylbutyl)sulfane
• CAS NO: 145075-36-1
• Molecular Weight: 210.34
• Mol File: 145075-36-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4(4-methoxyphenyl)(2-methylbutyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: 4(4-methoxyphenyl)(2-methylbutyl)sulfane(145075-36-1)
• EPA Substance Registry System: 4(4-methoxyphenyl)(2-methylbutyl)sulfane(145075-36-1)

Safety Data

• Hazardous Substances Data: 145075-36-1(Hazardous Substances Data)

Upstream product

• 20089-07-0 2-methyl-1-butanethiol 
• 696-62-8 para-iodoanisole 

Relevant articles and documents

A general rhodium-catalyzed cross-coupling reaction of thiols with aryl iodides

The general procedure for the rhodium-catalyzed cross-coupling of thiols with aryl iodides is described. The catalytic system consists of 5 mol % of [RhCl(cod)]2 and 10 mol % of PPh3 as a ligand. A variety of aryl iodides reacted with thiols, giving aryl thioethers in good to excellent yields. It is important to note that the deactivated aryl iodides such as 4-iodoanisole is worked smoothly to provide the corresponding aryl thioethers in excellent yields. Functional groups such as free-amines, chloro, are all tolerated under the employed reaction conditions.

CATALYTIC C-X-BOND METATHESIS THROUGH ARYLATION

The present invention refers to a process for a catalytic aryl transfer to rearrange the backbone of aromatic C-X bonds.