1450916-50-3Relevant articles and documents
Structure-Dependent Nickel-Catalysed Transposition of N -Allylamides to E- or Z-Enamides
Weber, Felicia,Steinlandt, Philipp S.,Ballmann, Monika,Hilt, Gerhard
, p. 440 - 450 (2016/12/24)
The nickel-catalysed transposition of a carbon-carbon double bond of N-allyl and N-homoallyl amides is described. While the transposition of acyclic amides gave very high Z-selectivity of the enamides, corresponding cyclic N-allyl amides led exclusively t
Easy access to enamides: A mild nickel-catalysed alkene isomerization of allylamides
Wang, Lu,Liu, Chao,Bai, Ruopeng,Pan, Yani,Lei, Aiwen
supporting information, p. 7923 - 7925 (2013/09/02)
The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an i