1450980-96-7

Basic information

• Product Name: 1-iodo-2-(2-methylcyclohex-2-enyloxy)benzene
• Synonyms: 1-iodo-2-(2-methylcyclohex-2-enyloxy)benzene
• CAS NO: 1450980-96-7
• Molecular Weight: 314.166
• Mol File: 1450980-96-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-iodo-2-(2-methylcyclohex-2-enyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-iodo-2-(2-methylcyclohex-2-enyloxy)benzene(1450980-96-7)
• EPA Substance Registry System: 1-iodo-2-(2-methylcyclohex-2-enyloxy)benzene(1450980-96-7)

Safety Data

• Hazardous Substances Data: 1450980-96-7(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 533-58-4 2-Iodophenol 
• 20461-30-7 2-methylcyclohex-2-en-1-ol 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 10409-47-9 2-bromo-2-methylcyclohexanone 

Downstream Products

• 1450981-00-6 1-allyl-2-(2-methylcyclohex-2-enyloxy)benzene 

Relevant articles and documents

Intramolecular carbonickelation of alkenes

The efficiency of the intramolecular carbonickelation of substituted allylic ethers and amines has been studied to evaluate the influence of the groups borne by the double bond on this cyclization. The results show that when this reaction takes place, it affords only the 5-exo-trig cyclization products, viz. dihydrobenzofurans or indoles. Depending on the tethered heteroatom (O or N), the outcome of the cyclization differs. While allylic ethers are relatively poor substrates that undergo a side elimination and need an intracyclic double bond to proceed, allylic amines react well and afford indoline and indole derivatives. Finally, the synthesis of the trinuclear ACE core of a morphine-like skeleton was achieved by using NiBr2bipy catalysis.