1451003-19-2Relevant academic research and scientific papers
Stimuli-responsive folding and unfolding of a polymer bearing multiple cerium(IV) bis(porphyrinate) joints: Mechano-imitation of the action of a folding ruler
Shibata, Masayuki,Tanaka, Satoshi,Ikeda, Tomohiro,Shinkai, Seiji,Kaneko, Kenji,Ogi, Soichiro,Takeuchi, Masayuki
, p. 397 - 400 (2013)
A pivotal guest role: A new porphyrin polymer, poly(PorZn·DD) (see picture, pink/purple), composed of a porphyrinatozinc and a porphyrin double-decker complex as a repeating unit was synthesized. In poly(PorZn·DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double-decker complexes and the polymer undergoes shortening and compaction.
