1451044-01-1Relevant academic research and scientific papers
Smectic mesophases of functionalized silver and gold nanoparticles with anisotropic plasmonic properties
Lewandowski, Wiktor,Constantin, Doru,Walicka, Kinga,Pociecha, Damian,Mieczkowski, Jozef,Gorecka, Ewa
, p. 7845 - 7847 (2013)
Silver and gold nanoparticle superlattices with a layered structure were obtained via grafting of mesogenic molecules onto a metallic cluster surface. For the Ag superstructures unusual orientational order of the mesogenic ligands and anisotropy of the assembly afforded tunable plasmonic properties.
Transient imine as a directing group for the metal-free o-C-H borylation of benzaldehydes
Rej, Supriya,Chatani, Naoto
supporting information, p. 2920 - 2929 (2021/03/01)
Organoboron reagents are important synthetic intermediates and have wide applications in synthetic organic chemistry. The selective borylation strategies that are currently in use largely rely on the use of transition-metal catalysts. Hence, identifying much milder conditions for transition-metal-free borylation would be highly desirable. We herein present a unified strategy for the selective C-H borylation of electron-deficient benzaldehyde derivatives using a simple metal-free approach, utilizing an imine transient directing group. The strategy covers a wide spectrum of reactions and (i) even highly sterically hindered C-H bonds can be borylated smoothly, (ii) despite the presence of other potential directing groups, the reaction selectively occurs at the o-C-H bond of the benzaldehyde moiety, and (iii) natural products appended to benzaldehyde derivatives can also give the appropriate borylated products. Moreover, the efficacy of the protocol was confirmed by the fact that the reaction proceeds even in the presence of a series of external impurities.
