1451046-02-8

Basic information

• Product Name: 3,4,6,7-tetrakis(p-methylbenzenesulfonyloxy)-9-hydroxyphenalenone
• CAS NO: 1451046-02-8
• Molecular Weight: 876.961
• Mol File: 1451046-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,4,6,7-tetrakis(p-methylbenzenesulfonyloxy)-9-hydroxyphenalenone(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6,7-tetrakis(p-methylbenzenesulfonyloxy)-9-hydroxyphenalenone(1451046-02-8)
• EPA Substance Registry System: 3,4,6,7-tetrakis(p-methylbenzenesulfonyloxy)-9-hydroxyphenalenone(1451046-02-8)

Safety Data

• Hazardous Substances Data: 1451046-02-8(Hazardous Substances Data)

Upstream product

• 1425265-57-1 3,4,6,7,9-pentahydroxyphenalen-1-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 17276-03-8 1,3,6,8-tetramethoxynaphthalene 
• 1335551-15-9 3-oxo-3-(2,4,5,7-tetramethoxynaphthalen-1-yl)propionic acid ethyl ester 
• 1425540-30-2 C₁₇H₁₆O₆ 

Relevant articles and documents

Synthesis of tetrachalcogenide-substituted phenalenyl derivatives: Preparation and solid-state characterization of bis(3,4,6,7-tetrathioalkyl- phenalenyl)boron Radicals

We report the synthesis and properties of a series of spiro-bis(3,4,6,7- tetrachalcogenide-substituted-phenalenyl)boron salts and two of the corresponding tetrathioalkyl-substituted spiro-bis(phenalenyl)boron radicals [tetrathiomethyl (10) and tetrathioethyl (11)] in which all of the active positions of the phenalenyl (PLY) nucleus are functionalized. In the solid state, radicals 10 and 11 exist as a weak π-dimers due to the steric congestion of the thioalkyl groups in the superimposed PLY units. As a result, the spins are localized in the isolated (nonsuperimposed) PLY rings, and the structure, magnetic susceptibility measurements, and band structure calculations confirm that these PLY units are unable to undergo strong intermolecular interaction as a result of the orientation of the thioalkyl groups.