1451062-76-2Relevant academic research and scientific papers
Catalytic regioselective oxidation of glycosides
Jaeger, Manuel,Hartmann, Marcel,De Vries, Johannes G.,Minnaard, Adriaan J.
supporting information, p. 7809 - 7812 (2013/08/23)
Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates. Copyright
SELECTIVE OXIDATION OF CARBOHYDRATES
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Page/Page column 15, (2014/01/09)
The invention relates to the field of carbohydrate chemistry. Provided is a process for the regioselective oxidation of a single secondary hydroxy function of a carbohydrate substrate comprising two or more secondary hydroxy functions, comprising contacting the carbohydrate substrate in a solvent in the presence of a transition metal catalyst complex with an oxidizing agent to yield a mono-oxidized carbohydrate.
