145107-77-3Relevant academic research and scientific papers
Metal Complexes of Functionalized Sulfur-Containing Ligands, IV. Oxidative Addition Reactions of (Ph3P)2Pt(η2-C2H4) with N-(Alkyl- and Arylsulfinyl) Phthalimides: Platinum(II) Sulfenato Complexes
Weigand, Wolfgang,Bosl, Gabriele
, p. 1165 - 1169 (2007/10/02)
The platinum(0) compound (Ph3P)2Pt(η2-C2H4) reacts with N-(alkyl- and arylsulfinyl)phthalimides R-S(O)-Nphth to give the trans-configurated sulfenato complexes (Ph3P)2Pt(Nphth), (3a - f).The compounds (3a - f) have been characterized by IR, 1H, 13C and 31P NMR spectroscopy, (3a - f) additionally by their FAB mass spectra.The oxidation of cis-(Ph3P)2Pt(SC4H9)(Nphth) (5) with m-chloroperbenzoic acid leads to a mixture of compounds containing cis-(Ph3P)2Pt(S(O)C4H9)(Nphth) (6) as a main product.N-Sulfinyl Phthalimides, Sulfenato Metal Complexes, Oxidative Addition Reaction, Platinum
