1451154-73-6

Basic information

• Product Name: ethyl 4-(benzyloxy)-3-fluorobenzoate
• Synonyms: ethyl 4-(benzyloxy)-3-fluorobenzoate
• CAS NO: 1451154-73-6
• Molecular Weight: 274.292
• Mol File: 1451154-73-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 4-(benzyloxy)-3-fluorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-(benzyloxy)-3-fluorobenzoate(1451154-73-6)
• EPA Substance Registry System: ethyl 4-(benzyloxy)-3-fluorobenzoate(1451154-73-6)

Safety Data

• Hazardous Substances Data: 1451154-73-6(Hazardous Substances Data)

Upstream product

• 124156-21-4 ethyl (4-methoxyphenylimino)acetate 
• 133057-83-7 4-benzyloxy-3-fluorophenylboronic acid 

Relevant articles and documents

An unusual 1,2-aryl shift in palladium-catalyzed cross-coupling ethoxycarbonylation of arylboronic acids with α-iminoesters

The Pd-catalyzed cross-coupling ethoxycarbonylation of aryl boronic acids with N-aryl-α-iminoesters affords aryl carboxylic esters via carbonyl-imino σ bond cleavage. This unprecedented mode of reaction allows regioselective installation of the ethoxycarbonyl group into target molecules. Mechanism studies have revealed that an unusual 1,2-aryl shift process is involved in the transformation. The Royal Society of Chemistry.