14513-43-0

Usage

Uses

Used in Pharmaceutical Industry:
3,3''-(1-METHYLETHYLIDENE)BIS-7-OXABICYCLO[4.1.0]HEPTANE is used as a key intermediate in the synthesis of various pharmaceuticals for its ability to contribute to the formation of complex molecular structures that can exhibit therapeutic properties.
Used in Fragrance Industry:
In the fragrance industry, 3,3''-(1-METHYLETHYLIDENE)BIS-7-OXABICYCLO[4.1.0]HEPTANE is used as a component in the creation of unique scents, leveraging its chemical structure to produce novel aroma compounds.
Used in Fine Chemicals Production:
3,3''-(1-METHYLETHYLIDENE)BIS-7-OXABICYCLO[4.1.0]HEPTANE is utilized as a building block in the production of fine chemicals, where its distinctive structure can be employed to develop specialty chemicals for various applications.
It is crucial to handle 3,3''-(1-METHYLETHYLIDENE)BIS-7-OXABICYCLO[4.1.0]HEPTANE with care due to potential health and safety risks, ensuring that proper handling and storage procedures are strictly followed to mitigate any risks associated with its use.

Upstream product

• 59095-15-7 4-(2-cyclohex-3-en-1-ylpropyl-2-yl)cyclohexene 
• 13804-54-1 4,4'-isopropylidenedicyclohexanol 

Relevant academic research and scientific papers

Continuous preparation method of alicyclic epoxy compound

The invention provides a continuous preparation method of an alicyclic epoxy compound. The preparation method comprises the following steps: S1, continuously introducing alicyclic olefin and a hydrogen peroxide aqueous solution into a micro-emulsifier for emulsification to form an emulsion, the concentration of the hydrogen peroxide aqueous solution being greater than or equal to 8wt%; s2, continuously introducing the emulsified liquid into a microreactor for oxidation reaction to obtain a crude product mother solution; and S3, purifying the crude product mother liquor to obtain the alicyclic epoxy compound. According to the preparation method, the dynamic micro-channel reactor is adopted, the homogeneity of the reaction system is ensured through the combination of the micro-emulsifier and the micro-reactor, and the problem of poor mixing effect is avoided, so that relatively high reaction conversion rate and yield of alicyclic epoxy compound preparation can be realized by adopting the low-concentration hydrogen peroxide aqueous solution as the oxidizing agent. Besides, a continuous operation process is adopted, so that the process is small in danger, safe and controllable.

Safe, environment-friendly and controllable synthetic process of di-epoxide

The invention relates to the field of synthesis of epoxide, and more specifically, relates to a safe, environment-friendly and controllable synthetic process of di-epoxide. The synthetic process of the di-epoxide at least comprises the following steps: mixing diolefin, carboxylic acids, basic salt and solvent, and cooling; dropwise adding a hydrogen peroxide solution for 1-12 h; standing for layering to obtain a lower layer organic phase-1, washing the organic phase-1 with a cleaning solution, and standing for layering to obtain a lower layer organic phase-2; purifying. The reaction system ofthe synthetic process is simple, environmentally friendly, safe and controllable, is low in production cost, and can meet the requirements of technical economy; the prepared di-epoxide is high in purity and yield and low in solvent content, chroma and halogen content, and is suitable for large-scale industrial production.

Bicyclic oxide preparation method (by machine translation)

The present invention provides bicyclic oxide preparation method, the invention bicyclic oxide catalysting preparation method comprises, hydrogen peroxide and a buffer in the presence of a diene compound epoxidation to prepare bicyclic oxide step. (by machine translation)

PHOTOCURABLE COMPOSITION, CURED PRODUCT AND OPTICAL COMPONENT USING SAME

Provided is a photocurable composition which less causes resin-induced swelling of molds, allows the molds to endure more satisfactorily, and has excellent economic efficiency. This photocurable composition includes components (A), (B), (C), and (D). The component (A) is present in a content of 10 to 50 weight percent of the totality of photocurable compounds contained in the photocurable composition. The component (A) is a cycloaliphatic epoxy compound represented by Formula (a). The component (B) is an oxetane compound having a solubility parameter of 9.5 (cal/cm3)1/2 or more as determined by the Fedors' method. The component (C) is a glycidyl ether epoxy compound having a molecular weight of 250 or more. The component (D) is a photoinitiator: wherein R1 to R18 are each, identically or differently, selected from hydrogen, halogen, a hydrocarbon group optionally containing oxygen or halogen, and optionally substituted alkoxy; and X is selected from a single bond and a linkage group.

HIGH-PURITY ALICYCLIC DIEPOXY COMPOUND AND PROCESS FOR PRODUCING THE SAME

A high-purity cycloaliphatic diepoxy compound of General Formula (II) is an epoxidized product of a cycloaliphatic diolefinic compound of General Formula (I) having an isomer content as detected in gas chromatography (GC) of 15% or less: wherein X represents a bivalent group selected from the group consisting of, for example, O, S, -SO-, -SO2-, -CH2-, and -C(CH3)2-; and R1 to R18 may be the same as or different from each other and each represent hydrogen atom, a halogen atom, a hydrocarbon group which may contain oxygen atom or a halogen atom, or an alkoxy group which may be substituted. Such a high-purity cycloaliphatic diepoxy compound is prepared by producing the cycloaliphatic diolefinic compound through distillation, epoxidizing the compound with an aliphatic percarboxylic acid containing substantially no water, carrying out desolvation, and further purifying the epoxidized compound through distillation.

HIGH-PURITY ALICYCLIC EPOXY COMPOUND, PROCESS FOR PRODUCING THE SAME, CURABLE EPOXY RESIN COMPOSITION, CURED ARTICLE THEREOF, AND USE

The present invention provides a high-purity alicyclic epoxy compound in which an alicyclic olefin compound is epoxidized with an aliphatic percarboxylic acid having substantially no water followed by the removal of a solvent to produce an alicyclic epoxy compound represented by the general formula (I) that is in turn subjected to purification by distillation to thereby the high-purity alicyclic epoxy compound wherein the concentration of high-molecular-weight components having an elution time shorter than that of the alicyclic epoxy compound in detection by a GPC analysis is 5.5% or less in terms of the area ratio, the concentration of impurities having a retention time shorter than that of the alicyclic epoxy compound in detection by a GC analysis is 19.5% or less in terms of the area ratio, the concentration of reactive intermediates is 4.5% or less in terms of the area ratio, and a color hue (APHA) is 60 or less; a process of efficiently producing the same by the use of a low-toxicity solvent; a curable resin composition using the same; a cured product; and applications.