145182-22-5Relevant academic research and scientific papers
CHARACTERISRICS OF THE REACTION OF DIETHYL-3-PYRIDYLPHOSPHITE WITH ELECTROPHILIC REAGENTS
Onys'ko, P. P.,Suvalova, E. A.,Chudakova, T. I.,Sinitsa, A. D.
, p. 473 - 477 (2007/10/02)
The reactions of diethyl-3-pyridylphosphite with sulfur, phenyl azide, and chloral lead to the corresponding thio-, imino-, and vinyl phosphate.In the interaction with acyl chlorides, trinitrophenyl halides, or boron trifluoride etherate, cleavage of the HtO-P(III) bond occurs.Methyl iodide and triethyloxonium tetrafluoroborate react at the nitrogen atom.In 3-pyridylchlorovinylethyl phosphate, spotaneous O-N migration of the ethyl group, leading to betaine was detected.
