14519-11-0

Basic information

• Product Name: MAGNESIUM BROMIDE AR
• Synonyms: MAGNESIUM BROMIDE AR
• CAS NO: 14519-11-0
• Molecular Formula: BrHMg
• Molecular Weight: 105.22
• Mol File: 14519-11-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: MAGNESIUM BROMIDE AR(CAS DataBase Reference)
• NIST Chemistry Reference: MAGNESIUM BROMIDE AR(14519-11-0)
• EPA Substance Registry System: MAGNESIUM BROMIDE AR(14519-11-0)

Safety Data

• Hazardous Substances Data: 14519-11-0(Hazardous Substances Data)

Upstream product

• 4294-57-9 para-methylphenylmagnesium bromide 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Relevant articles and documents

SYNTHESIS OF BORONIC ESTERS AND BORONIC ACIDS USING GRIGNARD REAGENTS

Boronic esters and boronic acids are synthesized at ambient temperature in an ethereal solvent by the reaction of Grignard reagents with a boron-containing substrate. The boron-containing substrate may be a boronic ester such as pinacolborane, neopentylglycolborane, or a dialkylaminoborane compound such as diisopropylaminoborane. The Grignard reagents may be preformed or generated from an alkyl, alkenyl, aryl, arylalkyl, heteroaryl, vinyl, or allyl halide compound and Mg°. When the boron-containing substrate is a boronic ester, the reactions generally proceed at room temperature without added base in about 1 to 3 hours to form a boronic ester compound. When the boron-containing substrate is a dialkylaminoborane compound, the reactions generally proceed to completion at 0°C in about 1 hour to form a boronic acid compound.