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  • 1451929-33-1 Structure
  • Basic information

    1. Product Name: C22H24N2
    2. Synonyms: C22H24N2
    3. CAS NO:1451929-33-1
    4. Molecular Formula:
    5. Molecular Weight: 316.446
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1451929-33-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: C22H24N2(CAS DataBase Reference)
    10. NIST Chemistry Reference: C22H24N2(1451929-33-1)
    11. EPA Substance Registry System: C22H24N2(1451929-33-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1451929-33-1(Hazardous Substances Data)

1451929-33-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1451929-33-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,5,1,9,2 and 9 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1451929-33:
(9*1)+(8*4)+(7*5)+(6*1)+(5*9)+(4*2)+(3*9)+(2*3)+(1*3)=171
171 % 10 = 1
So 1451929-33-1 is a valid CAS Registry Number.

1451929-33-1Relevant articles and documents

Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclobutanes

Chen, Xiang,Chen, Lili,Zhao, Hongliang,Gao, Qian,Shen, Zhenlu,Xu, Senmiao

, p. 1533 - 1537 (2020)

We herein report the first example of iridium-catalyzed enantioselective C(sp3)–H borylation of cyclobutanes using benzoxazoline as the directing group. The combination of a chiral bidentate boryl ligand and an iridium precursor has found to effectively catalyze C(sp3)–H borylation to afford a variety of cyclobutylboronates with good to excellent enantioselectivities. We also demonstrate the synthetic utility of the current method by converting the stereogenic C—B bond to other functionalities.

Copper-free asymmetric allylic alkylation with a grignard reagent: Design of the ligand and mechanistic studies

Grassi, David,Dolka, Chrysanthi,Jackowski, Olivier,Alexakis, Alexandre

supporting information, p. 1466 - 1475 (2013/02/25)

The Cu-free asymmetric allylic alkylation, catalysed by NHC, with Grignard reagents is reported on allyl bromide derivatives with good results. The enantioselectivity was quite homogeneous (around 85 % ee) on large and various substrates, regardless of the nature of the Grignard reagent. The formation of stereogenic quaternary centres was highly regioselective for both aliphatic and aromatic derivatives with good enantiomeric excess (up to 92 % ee). The methodology developed was found to be complementary with the Cu-catalysed version. Several new NHCs were tested with improved efficiency. In addition, mechanistic studies, using NMR spectroscopy, led to the discovery of the catalytically active species. Copyright

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