1452219-94-1

Basic information

• Product Name: 3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione
• Synonyms: 3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione
• CAS NO: 1452219-94-1
• Molecular Weight: 390.438
• Mol File: 1452219-94-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione(1452219-94-1)
• EPA Substance Registry System: 3-([1,1'-biphenyl]-4-yl)-3-phenylisochroman-1,4-dione(1452219-94-1)

Safety Data

• Hazardous Substances Data: 1452219-94-1(Hazardous Substances Data)

Upstream product

• 92965-01-0 methyl 2-(2-oxo-2-phenylacetyl)benzoate 
• 5122-94-1 4-biphenylboronic acid 

Relevant articles and documents

Rhodium-catalyzed enantioselective addition to unsymmetrical α-diketones: Tandem one-pot synthesis of optically active 3-tetrasubstituted isochroman derivatives

The domino effect: An efficient and general catalytic one-pot synthesis of quaternary-substituted isochroman derivatives has been developed (see scheme). The cascade transformation relies on rhodium-catalyzed highly regio- and enantioselective 1,2-addition of arylboronic acids to unsymmetrical α-diketones and intramolecular etherification or esterification, and provides a variety of enantioenriched isochromanones under exceptionally mild conditions. Copyright