145223-04-7

Upstream product

• 59239-06-4 hex-5-en-2-one oxime 
• 34837-55-3 Phenylselenyl bromide 

Downstream Products

• 145223-11-6 (6S,8aS)-2,8a-Dimethyl-6-phenylselanylmethyl-hexahydro-dipyrrolo[1,2-b;3',4'-d]isoxazole-1,3-dione 
• 145223-08-1 3,4-dihydro-5-methyl-2-<(phenylseleno)methyl>-2H-pyrrole 1-oxide 
• 145223-09-2 5,6-dihydro-3-methyl-6-<(phenylseleno)methyl>-4H-1,2-oxazine 

Relevant academic research and scientific papers

Phenylselenyl Halide Induced Formation of Cyclic Nitrones from Alkenyl Oximes

Oximes possessing alk-γ- or -δ-enyl substituents are cyclised by phenylselenyl bromide, or by phenylselenyl chloride and an appropriate silver salt, to the corresponding cyclic nitrones; the seleno nitrones undergo facially specific cycloadditions with N-methylmaleimide, bis(alk-γ,δ-enyl) and bis(alk-δ,δ-enyl) ketones undergo regiospecific cyclisation and stereospecific cycloaddition to furnish spirocyclic products.