145251-92-9Relevant academic research and scientific papers
Synthesis of formylsilanes through oxidative cleavage of α-silyl glycols
Von Wachenfeldt, Henrik,Strand, Daniel
, p. 12268 - 12273 (2013)
A convenient method for the synthesis and isolation of highly reactive formylsilanes by oxidative cleavage of α-silyl glycols is presented. The mild conditions provide an entry to acid- and heat-sensitive members of this theoretically intriguing class of compounds. The utility of the method is demonstrated through the isolation and subsequent diastereoselective derivatization of t-BuMe2- and t-BuPh2-formylsilanes, previously not reported in isolated form.
