145259-91-2

Basic information

• Product Name: Benzoic acid (2S,3R,4R,4aS,10aR)-3-acetylamino-2-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-yl ester
• Synonyms: Benzoic acid (2S,3R,4R,4aS,10aR)-3-acetylamino-2-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-yl ester
• CAS NO: 145259-91-2
• Molecular Weight: 657.952
• Mol File: 145259-91-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (2S,3R,4R,4aS,10aR)-3-acetylamino-2-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (2S,3R,4R,4aS,10aR)-3-acetylamino-2-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-yl ester(145259-91-2)
• EPA Substance Registry System: Benzoic acid (2S,3R,4R,4aS,10aR)-3-acetylamino-2-benzyloxy-6,6,8,8-tetraisopropyl-hexahydro-1,5,7,9-tetraoxa-6,8-disila-benzocycloocten-4-yl ester(145259-91-2)

Safety Data

• Hazardous Substances Data: 145259-91-2(Hazardous Substances Data)

Upstream product

• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 
• 69304-37-6 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 
• 618-32-6 Benzoyl bromide 
• 82743-82-6 benzyl 2-acetamido-2-deoxy-4,6-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranoside 

Downstream Products

• 143836-21-9 Benzyl 2-acetamido-3-O-benzoyl-2-deoxy-4,6-O-<1-(methoxycarbonyl)ethylidene>-α-D-glucopyranoside 

Relevant articles and documents

Convenient synthesis of 4,6-O-pyruvate acetal containing glycosides via tetraisopropyldisiloxanediyl protected sugars

Treatment of alkyl D-glycopyranosides and alkyl or phenyl 1-thio-β-D-glycopyranosides 1 with 1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane gave the corresponding 4,6-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl) protected glycosides 2 which were subsequen