145276-90-0Relevant academic research and scientific papers
Iodobenzene catalyzed C-H amination of N-substituted amidines using m-chloroperbenzoic acid
Alla, Santhosh Kumar,Kumar, Rapolu Kiran,Sadhu, Pradeep,Punniyamurthy, Tharmalingam
supporting information, p. 1334 - 1337 (2013/04/23)
The oxidative C-H amination of N″-aryl-N′-tosyl/N′- methylsulfonylamidines and N,N′-bis(aryl)amidines has been accomplished using iodobenzene as a catalyst to furnish 1,2-disubstituted benzimidazoles in the presence of mCPBA as a terminal oxidant at room temperature. The reaction is general, and the target products can be obtained in moderate to high yields.
