1452796-22-3Relevant academic research and scientific papers
Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones: Total synthesis of (-)-aspidospermidine and (+)-kopsihainanineA
Li, Zeqian,Zhang, Shaoxiong,Wu, Shoutao,Shen, Xiaolei,Zou, Liwei,Wang, Fengqun,Li, Xiang,Peng, Fangzhi,Zhang, Hongbin,Shao, Zhihui
supporting information, p. 4117 - 4121 (2013/05/08)
Functionalized chiral carbazolones with α-quaternary carbon centers are formed through the ligand-controlled Pd-catalyzed enantioselective decarboxylative allylic alkylation of carbazolones (see scheme). This catalytic asymmetric reaction was employed as the key step in the total synthesis of aspidospermidine and (+)-kopsihainanineA. Copyright
