1452862-77-9Relevant academic research and scientific papers
C-H arylation of 3-substituted thiophene with regioselective deprotonation by tmpMgCl·LiCl and transition metal catalyzed cross coupling
Tanaka, Shota,Tamba, Shunsuke,Sugie, Atsushi,Mori, Atsunori
, p. 255 - 266 (2013/08/23)
The reaction of 3-hexylthiophene with Knochel-Hauser base (TMPMgCl·LiCl) induced the metalation at the 5-position of the thiophene ring selectively. Following addition of several aryl halides in the presence of a nickel or palladium catalyst afforded regi
