145315-69-1

Basic information

• Product Name: 5-(tert-Butyl-diphenyl-silanyl)-pent-1-en-3-one
• Synonyms: 5-(tert-Butyl-diphenyl-silanyl)-pent-1-en-3-one
• CAS NO: 145315-69-1
• Molecular Weight: 322.522
• Mol File: 145315-69-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-(tert-Butyl-diphenyl-silanyl)-pent-1-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(tert-Butyl-diphenyl-silanyl)-pent-1-en-3-one(145315-69-1)
• EPA Substance Registry System: 5-(tert-Butyl-diphenyl-silanyl)-pent-1-en-3-one(145315-69-1)

Safety Data

• Hazardous Substances Data: 145315-69-1(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 62418-65-9 Triethyl<(1,4-pentadien-3-yl)oxy>silan 
• 145315-67-9 C₂₇H₄₀OSi₂ 

Downstream Products

• 86119-05-3 5'-methyl-6'-oxo-4',6',7',8'-tetrahydro-3'H-spiro[[1,3]dioxolane-2,2'-naphthalene]-8'a-carboxylic acid methyl ester 
• 145315-76-0 5'-[(tert-Butyl-diphenyl-silanyl)-methyl]-1',3',4',7',8',8'a-hexahydro-spiro[[1,3]dioxolane-2,2'-naphthalen]-6'-one 
• 149765-13-9 5'-[(tert-Butyl-diphenyl-silanyl)-methyl]-6'-oxo-4',6',7',8'-tetrahydro-3'H-spiro[[1,3]dioxolane-2,2'-naphthalene]-8'a-carboxylic acid methyl ester 

Relevant articles and documents

Oxidation and reduction reactions of highly functionalized allyl stannanes. Bicyclic and tricyclic α-stannylmethyl enones prepared via the Robinson annulation reaction of β′-stannylethyl vinyl ketone

5-(Tributylstannyl)-1-penten-3-one is prepared in 50% overall yield from the readily available 3-((triethylsilyl)-oxy)-1,4-pentadiene. Use of this reagent in the Robinson annulation reaction provides α-stannylmethyl enones in very good yields. Cerium-medi