1453217-43-0

Basic information

• Product Name: C₁₆H₈O₁₀S^(2-)*C₁₂H₈N₂*Cd⁽²⁺⁾
• Synonyms: C₁₆H₈O₁₀S^(2-)*C₁₂H₈N₂*Cd⁽²⁺⁾
• CAS NO: 1453217-43-0
• Molecular Weight: 684.918
• Mol File: 1453217-43-0.mol

Chemical Properties

• CAS DataBase Reference: C₁₆H₈O₁₀S^(2-)*C₁₂H₈N₂*Cd⁽²⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₈O₁₀S^(2-)*C₁₂H₈N₂*Cd⁽²⁺⁾(1453217-43-0)
• EPA Substance Registry System: C₁₆H₈O₁₀S^(2-)*C₁₂H₈N₂*Cd⁽²⁺⁾(1453217-43-0)

Safety Data

• Hazardous Substances Data: 1453217-43-0(Hazardous Substances Data)

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 10595-31-0 3,3’,4,4’-diphenylsulfonetetracarboxylic acid 

Relevant articles and documents

PH modulated assembly in the mixed-ligand system Cd(ii)-dpstc-phen: Structural diversity and luminescent properties

Hydrothermal reaction of cadmium salt, 3,3′,4,4′- diphenylsulfonetetracarboxylic acid (H4dpstc) and 1,10-phenanthroline (phen) under different pH conditions have afforded four novel supramolecular complexes, in which the pH value of the reaction solution plays a crucial structure-directing role. [Cd(H2dpstc)(phen)]n (1) formed in a neutral reaction environment exhibits a 1D infinite chain structure containing partially deprotonated H2dpstc2- as the H-bond donors and acceptors. Whereas [Cd2(dpstc)(phen)2] n·4.5nH2O (2), [Cd2(dpstc)(phen) 2]n·nH2O (3) and [Cd2(dpstc) (phen)4(H2O)2]·6H2O (4) contain fully deprotonated dpstc4- ligands due to the alkaline reaction conditions. Complex 2 possesses a unique 2D layered structure with 1D channels. The most striking feature of 2 is that its 2D holed (4,4)-water-net is constructed from hexameric water clusters and two types of dimeric water clusters. Surprisingly, the water net and the metal-organic skeleton are interpenetrated to form a fascinating 3D metal-organic-water supramolecular architecture. A further increase of the pH value leads to another 2D layered framework of 3 containing dumbbell-shaped rings as subunits. Reaction at a strongly alkaline solution leads to a discrete molecule of 4. Meanwhile solid-state properties such as thermal stability and the photoluminescence properties at room temperature for these complexes have also been systematically investigated.