1453262-41-3

Upstream product

• 1453262-39-9 C₄₉H₅₂FeO₂Si 

Downstream Products

• 1453262-51-5 1-(N-methylaminomethyl)-2-(2,3,4,5-tetraphenylcyclopenta-2,4-dien-1-yl)ferrocene 
• 1453262-50-4 1-(N,N-dimethylaminomethyl)-2-(2,3,4,5-tetraphenylcyclopenta-2,4-dien-1-yl)ferrocene 
• 1453262-54-8 (pS)-1-[(diphenylphosphino)methyl]-2-(2,3,4,5-tetraphenylcyclopenta-1,3-dien-1-yl)ferrocene 

Relevant academic research and scientific papers

Synthesis of planar chiral ferrocenyl cyclopentadienyl chelate ligand precursors

Two families of planar chiral ferrocenyl cyclopentadienyl chelate ligands for use in ansa-half sandwich metallocene complexes of catalytically active transition metals are described. The first family was derived in 4-5 steps from an enzymatic resolution of 1-iodo-2-(methylalcohol)ferrocene and possesses a cyclopentadiene derivative [Cp(H) = 1-indenyl, 2-indenyl or Ph4Cp(H)] directly attached to the ferrocene ring with an adjacent vicinal tether CH 2Z donor group (Z = OH, OMe, NHMe, NMe2 or PPh 2). The second family was derived from a chiral auxiliary approach and has the donor group (Z = PPh2 or NMe2) attached directly to the ferrocene ring with an adjacent tether vicinal CH 2Cp(H) group [Cp(H) = Cp(H), fluorenyl, 1-indenyl, Me 4Cp(H) or Ph4Cp(H)].