1453503-98-4

Basic information

• Product Name: 4-(2-{[(1,1-dimethylethyl)dimethyl]silyl}ethynyl)anisole
• Synonyms: 4-(2-{[(1,1-dimethylethyl)dimethyl]silyl}ethynyl)anisole
• CAS NO: 1453503-98-4
• Molecular Weight: 246.425
• Mol File: 1453503-98-4.mol

Chemical Properties

• CAS DataBase Reference: 4-(2-{[(1,1-dimethylethyl)dimethyl]silyl}ethynyl)anisole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2-{[(1,1-dimethylethyl)dimethyl]silyl}ethynyl)anisole(1453503-98-4)
• EPA Substance Registry System: 4-(2-{[(1,1-dimethylethyl)dimethyl]silyl}ethynyl)anisole(1453503-98-4)

Safety Data

• Hazardous Substances Data: 1453503-98-4(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 86318-61-8 (tert-butyldimethylsilyl)acetylene 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 768-60-5 4-methoxyphenylacetylen 
• 106-37-6 1.4-dibromobenzene 
• 16116-78-2 (4-bromophenyl)(trimethylsilyl)acetylene 

Downstream Products

• 1261079-22-4 1,3,4-tris(4-methoxyphenyl)-1H-pyrrole-2-carbaldehyde 
• 1453503-99-5 (E)-3-((tert-butyldimethylsilyl)(4-methoxyphenyl)methylene)-2-(1H-pyrrol-1-yl)isoindolin-1-one 
• 1453504-00-1 (Z)-3-((tert-butyldimethylsilyl)(4-methoxyphenyl)methylene)-2-(1H-pyrrol-1-yl)isoindolin-1-one 
• 1453504-10-3 4-(tert-butyldimethylsilyl)-3-(4-methoxyphenyl)-2-(1H-pyrrol-1-yl)isoquinolin-1(2H)-one 

Relevant articles and documents

Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings

A series of bis(pyrazolyl)methane copper complexes were found to catalyze a fast palladium-free Sonogashira coupling reaction of several iodoarenes with terminal alkynes such as phenylacetylene, propargyl benzyl ether, and (tert-butyl-dimethyl)silylacetyl

Trimethylsilyl-Protected Alkynes as Selective Cross-Coupling Partners in Titanium-Catalyzed [2+2+1] Pyrrole Synthesis

Trimethylsilyl (TMS)-protected alkynes served as selective alkyne cross-coupling partners in titanium-catalyzed [2+2+1] pyrrole synthesis. Reactions of TMS-protected alkynes with internal alkynes and azobenzene under the catalysis of titanium imido comple