1453803-68-3Relevant articles and documents
Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes
Sawano, Takahiro,Ou, Keiyu,Nishimura, Takahiro,Hayashi, Tamio
, p. 8986 - 8993 (2013/10/08)
The asymmetric addition of silylacetylenes to 1,1-disubstituted allenes proceeded in the presence of a cobalt/chiral bisphosphine ligand to give the corresponding enynes with high enantioselectivity. The results of deuterium-labeling experiments indicated