145386-47-6

Upstream product

• 10198-27-3 2-(2-hydroxyethyl)-cyclohexan-1-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 288-32-4 1H-imidazole 
• 76593-65-2 1-(Hexahydro-benzofuran-7a-yl)-pyrrolidine 

Downstream Products

• 944382-60-9 2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate 
• 201035-92-9 1-[5'-(3''-iodo-propan-1''-yl)-2'-furanyl]-2'-(2'''-oxo-but-3'''-yn-1'''-yl)cyclohex-6-ene 
• 944382-79-0 1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]-2'-(2'''-oxo-but-3'''-yn-1'''-yl)cyclohex-6-ene 
• 944382-78-9 1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]-2'-(2'''-hydroxy-but-3'''-yn-1'''-yl)cyclohex-6-ene 
• 944382-77-8 1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]-2'-(2'''-oxo-ethan-1'''-yl)cyclohex-6-ene 
• 944382-76-7 1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]-2'-(2'''-hydroxy-ethan-1'''-yl)cyclohex-6-ene 
• 944382-61-0 2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene 
• 944382-82-5 C₁₇H₂₄O₄ 
• 944382-75-6 2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-tert-butyldiphenylsilyloxy-propan-1''-yl)-2'-furanyl]-cyclohex-6-ene 
• 944382-74-5 1-[5'-(3''-tert-butyldiphenylsilyloxy-propan-1''-yl)-2'-furanyl]-2-(2'''-hydroxy-ethan-1'''-yl)-cyclohex-6-ene 
• 1026898-87-2 C₃₇H₅₄O₃Si₂ 

Relevant academic research and scientific papers

Cascade radical-mediated cyclisations with conjugated ynone electrophores. An approach to the synthesis of steroids and other novel ring-fused polycyclic carbocycles

A cascade radical-mediated Diels-Alder reaction with the iododienynone 16b produced the tricyclic ketone 17 (22%). By contrast, treatment of the substituted furans 36 and 47 with Bu3SnH-AIBN, instead led to the tetracycles 44 and 58 respectivel

Tricyclic or tetracyclic carbapenem compounds, their production and use

A polycyclic carbapenem compound of the formula (Ia'), (Ib') or (Ic') STR1 [wherein COOR2 is a carboxy group which may be esterified; Ra' is --(CH2)m --Ka --(CH2)n --Ua' ; J is O or S; Rb' is --(CH2)m --Kb --(CH2)n Ub' ; J' is O, S or CH2 ; Rc' is --(CH2)m --Kc --(CH2)n --Uc', --(CH2)m --Kd --(CH2)n --Ud or a pair of groups, one of which is a hydroxy group, with the other being a hydroxzy group or an alkylsulfonylamino group, which may be substituted, in the position ortho to the first-mentioned hydroxy group] or a salt thereof are useful as an antibacterial agent.