1453868-10-4Relevant academic research and scientific papers
Total synthesis and structural revision of sekothrixide
Terayama, Naoki,Yasui, Eiko,Mizukami, Megumi,Miyashita, Masaaki,Nagumo, Shinji
supporting information, p. 2794 - 2797 (2014/06/23)
The first total synthesis of 14-membered macrolide sekothrixide and the originally proposed structure are reported. Seven contiguous asymmetric centers in the side chain were constructed using ring-openings of several kinds of epoxide. Assembly of the lef
Stereocontrolled synthesis of 1,3-diols from enones: Cooperative lewis base-mediated intramolecular carbonyl hydrosilylations
Medina, Casey,Carter, Kyle P.,Miller, Michael,Clark, Timothy B.,O'Neil, Gregory W.
, p. 9093 - 9101 (2013/10/08)
A streamlined synthesis of β-hydroxy ketone substrates has been developed to further investigate a recently discovered cooperative Lewis base-mediated intramolecular carbonyl hydrosilylation reaction. The synthesis features an enone β-borylation/oxidation
