1454799-47-3

Basic information

• Product Name: O-ethyl-S-[(((methyl 2,3,6-tri-O-benzyl-α-D-glucopyranos-4-yl)dimethylsilyl)methyl)]dithiocarbonate
• CAS NO: 1454799-47-3
• Molecular Weight: 656.937
• Mol File: 1454799-47-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-ethyl-S-[(((methyl 2,3,6-tri-O-benzyl-α-D-glucopyranos-4-yl)dimethylsilyl)methyl)]dithiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: O-ethyl-S-[(((methyl 2,3,6-tri-O-benzyl-α-D-glucopyranos-4-yl)dimethylsilyl)methyl)]dithiocarbonate(1454799-47-3)
• EPA Substance Registry System: O-ethyl-S-[(((methyl 2,3,6-tri-O-benzyl-α-D-glucopyranos-4-yl)dimethylsilyl)methyl)]dithiocarbonate(1454799-47-3)

Safety Data

• Hazardous Substances Data: 1454799-47-3(Hazardous Substances Data)

Upstream product

• 19488-48-3 methyl O-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 140-89-6 potassium ethyl xanthogenate 

Downstream Products

• 58341-66-5 methyl 2,6-di-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

A tin-free regioselective radical de-o-benzylation by an intramolecular hydrogen atom transfer on carbohydrate templates

Radically selective: A remarkable 1,7-hydrogen atom transfer of a benzylic hydrogen atom to an O-silylmethylene radical initiates a regioselective de-O-benzylation of benzylated saccharides. The reaction terminates by an ionic mechanism and is general for hydroxy benzylated substrates having a variety of functional groups. Copyright