1454915-90-2

Upstream product

• 1454915-77-5 C₁₄H₂₀O₂ 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 1454915-75-3 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetaldehyde 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 1454915-74-2 ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate 
• 1454915-73-1 ethyl 2-((1R,2S,6S)-2-hydroxy-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-en-1-yl)acetate 
• 1454915-72-0 ethyl 2-((1R,6S)-3-methyl-2-oxo-6-(prop-1-en-2-yl)cyclohex-3-en-1-yl)acetate 

Downstream Products

• 1454915-91-3 C₂₂H₃₈O₃Si 

Relevant academic research and scientific papers

What controls stereoselectivity and reactivity in the synthesis of a trans -decalin with a quaternary chiral center via the intramolecular Pauson-Khand reaction: A theoretical study

The Co2(CO)8-mediated intramolecular Pauson-Khand reaction is an efficient approach to the trans-decalin subunit with a defined C1 quaternary chiral center. The newly developed density functional theory method M11-L was employed to s

Development of an expedient intramolecular Pauson-Khand reaction approach to stereoselectively construct the trans-decalin with a C1 quaternary chiral center

Stereoselective synthesis of the trans-decalin subunit with a defined C1 quaternary chiral center has been achieved by the Pauson-Khand reaction (PKR) as a key step. The developed chemistry offers an alternative to the IMDA reaction that has been used for the syntheses of trans-decalin based biologically active natural products. The Royal Society of Chemistry 2013.