1455017-35-2Relevant academic research and scientific papers
Cu-catalyzed debrominative cyanation of gem-dibromoolefins: A facile access to α,β-unsaturated nitriles
Ahuja, Brij Bhushan,Sudalai, Arumugam
, p. 5918 - 5923 (2015/06/02)
An efficient catalytic route for the synthesis of α,β-unsaturated nitriles from easily accessible gem-dibromoolefins has been developed. The method utilized inexpensive reagents such as Cu2O as a catalyst, l-proline as a ligand and NaCN as a cyanide source to afford α,β-unsaturated nitriles in high yields (62-86%). A deuterium exchange study has shown that one of the bromide atoms of gem-dibromoolefins exchanges with cyanide while the other with a deuterium atom.
CUCN-MEDIATED ONE POT PRODUCTION OF CINNAMONITRILE DERIVATIVES
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Paragraph 0046 - 0048; 0057, (2015/02/19)
The present invention discloses a cheaper and practical protocol for the construction of a wide variety of o-cyanocin-namonitrile and their structural analogues that proceeds with good yields in a single step using CuCN as the only reagent.
CUCN-MEDIATED ONE POT PRODUCTION OF CINNAMONITRILE DERIVATIVES
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Page/Page column 8; 9; 11; 12, (2013/09/26)
The present invention discloses a cheaper and practical protocol for the construction of a wide variety of o-cyanocinnamonitrile and their structural analogues that proceeds with good yields in a single step using CuCN as the only reagent.
