1455438-47-7Relevant academic research and scientific papers
Asymmetric Synthesis of α-Amino Ketones by Bronsted Acid Catalysis
Wen, Wei,Zeng, Yu,Peng, Li-Yu,Fu, Li-Na,Guo, Qi-Xiang
, p. 3922 - 3925 (2015)
The highly efficient, regioselective, and enantioselective transfer hydrogenation of α-keto ketimines and reductive amination of diketones by Bronsted acid catalysis is described. A series of chiral α-amino ketones is prepared in high yields (up to >99%), excellent regioselectivities (up to >99:1), and enantioselectivities (up to 98% ee). This method has broad substrate scope.
Catalytic enantioselective Amadori-Heyns rearrangement of racemic α-hydroxy ketones with arylamines: Synthesis of optically active α-arylamino ketones
Frongia, Angelo,Secci, Francesco,Capitta, Francesca,Piras, Pier Paolo,Sanna, Maria Luisa
supporting information, p. 8812 - 8814 (2013/09/24)
A novel synthesis of optically active α-arylamino ketones through an organocatalytic enantioselective Amadori-Heyns rearrangement is described. The Royal Society of Chemistry 2013.
