1455468-16-2Relevant academic research and scientific papers
Intramolecular Paterno-Buechi reaction of atropisomeric α-oxoamides in solution and in the solid-state
Raghunathan, Ramya,Kumarasamy, Elango,Iyer, Akila,Ugrinov, Angel,Sivaguru
, p. 8713 - 8715 (2013)
Atropisomeric α-oxoamides were synthesized and employed for intramolecular Paterno-Buechi reaction leading to very high enantio- and diastereoselectivity in the bicyclic oxetane photoproduct. A reversal of product selectivity was observed in solution and in the solid-state.
