145587-40-2Relevant academic research and scientific papers
REACTION DES BASES CONJUGUEES DE PHOSPHORANES A LIAISON P-H SUR LES α-CETOACIDES. STABILISATION DES INTERMEDIAIRES REACTIONNELS
Munoz, Aurelio,Lamande, Lydia
, p. 263 - 272 (2007/10/02)
Triethylammonium salts of unusual α-phosphoranyl-α-hydroxyacids have been prepared by reacting hydridophosphoranes with pyruvic, phenylpyruvic and keto-2-glutaric acids, in the presence of triethylamine.These compounds react with phosphorus trichloride or (and) chloro-2-dioxaphospholane-1,3,2 giving new polynuclear spirophosphoranes.Key words: Hydridophosphoranes; α-phosphoranyl-α-hydroxyacids; polynuclear spirophosphoranes.
