145593-46-0

Basic information

• Product Name: 2-Pyrrolidinone, 3,3-dichloro-4-(chloromethyl)-1-[(4-methylphenyl)sulfonyl]-
• CAS NO: 145593-46-0
• Molecular Formula: C12H12Cl3NO3S
• Molecular Weight: 356.657
• Mol File: 145593-46-0.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Pyrrolidinone, 3,3-dichloro-4-(chloromethyl)-1-[(4-methylphenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyrrolidinone, 3,3-dichloro-4-(chloromethyl)-1-[(4-methylphenyl)sulfonyl]-(145593-46-0)
• EPA Substance Registry System: 2-Pyrrolidinone, 3,3-dichloro-4-(chloromethyl)-1-[(4-methylphenyl)sulfonyl]-(145593-46-0)

Safety Data

• Hazardous Substances Data: 145593-46-0(Hazardous Substances Data)

Upstream product

• 98088-48-3 1-(allyloxy)-1-phenylbut-3-ene 
• 145610-58-8 N-allyl-N-tosyl-α,α,α-trichloroacetamide 

Relevant articles and documents

Solid-supported catalysts for atom-transfer radical cyclization of 2- haloacetamides

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Ligand electronic effects on rates of copper mediated atom transfer radical cyclisation and polymerisation

The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated.

Atom Transfer Radical Cyclisations Mediated by the Grubbs Ruthenium Metathesis Catalyst

The commercially available ruthenium carbene complex RuCl 2(=CHPh)(PCy3)2 efficiently catalyses the cychsation of halo alkenes to γ-lactones and γ-lactams.

New reactivity patterns of copper(I) and other transition metal NHC complexes: application to ATRC and related reactions

Pre-formed transition metal-NHC complex is shown to be an effective catalyst for Atom Transfer Radical Cyclisation (ATRC) reactions.