145646-63-5

Upstream product

• 108-98-5 thiophenol 
• 2250-64-8 1,1,1-trifluoro-2,2-bis(phenylthio)propane 

Downstream Products

• 221557-79-5 3,3-difluoro-2-phenyl-4-phenylsulfanyl-pent-4-en-2-ol 
• 245543-97-9 1,1-difluoro-2-phenylsulfonyl-1-propene 
• 1309789-37-4 C₂₀H₂₈F₂SSi 
• 1309789-36-3 C₁₄H₁₆F₂SSi 
• 1309789-35-2 C₁₉H₂₄F₂S 
• 1309789-34-1 C₁₈H₂₂F₂S 
• 1309789-33-0 C₁₇H₂₀F₂S 
• 1309789-32-9 C₁₆H₁₈F₂S 
• 1309789-31-8 C₁₉H₁₀F₈S 
• 1309789-30-7 C₁₈H₁₄F₂S 

Relevant academic research and scientific papers

Allylation of novel β-phenylthio substituted gem-difluoroallylic bromide to carbonyl compounds

The reaction of β-phenylthio substituted gem-difluoroallylic bromide 3 with aldehydes and ketones in the presence of Zn(Cu) in THF at reflux temperature afforded the corresponding homoallylic alcohols 4 in good yields.

Efficient Synthesis of Novel α-Aryl(alkyl)-β,β-difluorovinyl and α-Aryl(alkyl)-β-fluoro-β-perfluoroalkylvinyl Sulfides

Reaction of 1,1-bis(phenylthio)perfluoroalkyl aromatics or alkanes with a mixture of 2 equiv. of TiCl4 and 4 equiv. of LiAlH4 in THF at reflux temperature for 3 hours afforded α-aryl(alkyl)-β,β-difluorovinyl and α-aryl(alkyl)-β-fluoro-β-perfluoroalkylviny