145663-77-0

Basic information

• Product Name: 1-cyclododecanol
• Synonyms: 1-cyclododecanol
• CAS NO: 145663-77-0
• Molecular Weight: 356.957
• Mol File: 145663-77-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-cyclododecanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclododecanol(145663-77-0)
• EPA Substance Registry System: 1-cyclododecanol(145663-77-0)

Safety Data

• Hazardous Substances Data: 145663-77-0(Hazardous Substances Data)

Upstream product

• 7205-94-9 chloromethyl phenyl sulfoxide 
• 830-13-7 cyclododecanone 

Downstream Products

• 145663-83-8 2-(phenylsulfinyl)cyclotridecanone 

Relevant articles and documents

Generation of the α-Sulfinyl Carbenoid from α-Chloro Sulfoxides: A New Method for One-Carbon Homologation of Ketones to α-Sulfinyl Ketones

Treatment of 1-chloroalkyl phenyl sulfoxides with a base gave carbenoids rather than free carbenes.The carbenoids were successfully used in a new method for homologation of ketones to α-sulfinyl ketones.Treatment of the carbanion of chloromethyl phenyl sulfoxide with ketones gave the adducts, α-chloro β-hydroxy sulfoxides, in nearly quantitative yields. the adducts were treated with excess lithium diisopropylamide to give one-carbon homologated α-sulfinyl ketones via α-sulfinyl β-oxido carbenoids in moderate to good yields.This type of reaction was found not to occur with the corresponding sulfones.