1456728-89-4Relevant academic research and scientific papers
Palladium-catalyzed regio-selective oxidative C-H bond acylation of azoxybenzenes with alcohols
Hou, Lekai,Chen, Xiangxiang,Li, Shuang,Cai, Suxian,Zhao, Yanxia,Sun, Meng,Yang, Xiao-Juan
, p. 4160 - 4164 (2015)
A palladium-catalyzed regio-selective acylation of C-H bonds of azoxybenzenes with alcohols was developed using tert-butyl hydroperoxide (TBHP) as an oxidant. Alcohol derivatives can act as effective acyl precursors in situ, which are less toxic, inexpensive, stable, and commercially available. These transformations proceeded smoothly and could tolerate a variety of functional groups. This journal is
Merging Visible-Light Photocatalysis and Palladium Catalysis for C-H Acylation of Azo- and Azoxybenzenes with α-Keto Acids
Xu, Ning,Li, Pinhua,Xie, Zuguang,Wang, Lei
supporting information, p. 2236 - 2242 (2016/02/12)
An efficient C-H acylation of azo- and azoxybenzenes with α-keto acids has been developed by a combination of palladium catalysis and visible-light photoredox catalysis at room temperature under 1.5 W blue LED irradiation. This method tolerates a variety of disubstituted azo- and azoxybenzenes, as well as α-keto acids regardless of the nature of the substituents. A number of aryl ketones were obtained in good yields under mild reaction conditions.
Unprecedented ortho-acylation of azoxybenzenes with α-oxocarboxylic acids by Pd-catalyzed C-H activation and decarboxylation
Li, Hongji,Li, Pinhua,Zhao, Qiong,Wang, Lei
supporting information, p. 9170 - 9172 (2013/09/24)
A palladium-catalyzed ortho-acylation reaction of azoxybenzenes with α-oxocarboxylic acids was developed in the presence of K2S 2O8. The established methodology provides a direct approach to obtain acylated azoxybenzenes in good yields.
