1456896-27-7

Upstream product

• 1456896-16-4 2-fluoro-9,10-dioxo-9,10-dihydroanthracene-1,3-diyl bis(trifluoromethanesulfonate) 
• 98-80-6 phenylboronic acid 
• 2065-37-4 2-bromo-1,4-naphthoquinone 

Relevant academic research and scientific papers

Synthesis of arylated anthraquinones by site-selective Suzuki-Miyaura reactions of the bis(triflates) of 1,3-di(hydroxy)anthraquinones

Arylated anthraquinones were prepared by Suzuki-Miyaura reactions of the bis(triflates) of various 1,3-(dihydroxy)anthraquinones. While the reactions of the bis(triflates) of parent 1,3-(dihydroxy)anthraquinone and of 2-chloro-1,3-di(hydroxy)anthraquinone proceeded with very good site-selectivity, the corresponding reactions of the bis(triflate) of 2-fluoro-1,3- diarylanthraquinones were not site-selective, which was explained based on the π-donating effect of the fluorine atom.