145698-90-4Relevant academic research and scientific papers
Generation of trans-dioxoruthenium(VI) porphyrins: A photochemical approach
Zhang, Rui,Huang, Yan,Abebrese, Chris,Thompson, Helen,Vanover, Eric,Webb, Cathleen
experimental part, p. 152 - 157 (2011/11/06)
trans-Dioxoruthenium(VI) porphyrin complexes have been developed as one of the best-characterized model systems for heme-containing enzymes. Traditionally, this type of compounds can be prepared by oxidation of ruthenium(II) precursors with peroxyacids an
A facile photosynthesis of trans-dioxoruthenium(vi) porphyrins
Huang, Yan,Vanover, Eric,Zhang, Rui
, p. 3776 - 3778 (2010/08/07)
Photolysis of porphyrin-ruthenium(iv) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxoruthenium(vi) species bearing either sterically encumbered or unencumbered porphyrin ligands.
