145702-62-1Relevant academic research and scientific papers
Monomeric base-stabilized phosphino- and arsinoalanes
Atwood, David A.,Contreras, Leopoldo,Cowley, Alan H.,Jones, Richard A.,Mardones, Miguel A.
, p. 17 - 18 (2008/10/08)
The first base-stabilized phosphino- and arsinoalane monomers, H2AlEMes2·NMe3(Mes = mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95°C converts 1 to the trimer [H2AlPMes2]3 (3); further heating at 125°C results in the formation of Mes2PH and aluminum metal.
