145737-02-6

Basic information

• Product Name: 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole
• Synonyms: 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole
• CAS NO: 145737-02-6
• Molecular Weight: 226.302
• Mol File: 145737-02-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole(145737-02-6)
• EPA Substance Registry System: 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole(145737-02-6)

Safety Data

• Hazardous Substances Data: 145737-02-6(Hazardous Substances Data)

Upstream product

• 37488-45-2 1H-pyrrole-2-carbothioamide 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 295312-00-4 4-phenyl-2-(5'-formyl-1'H-pyrrol-2'-yl)thiazole-5-carbaldehyde 
• 295311-97-6 4-phenyl-2-(1'H-pyrrol-2'-yl)thiazole-5-carbaldehyde 

Relevant articles and documents

21,23-Dithia-3,13-diazaporphycenes - novel aromatic porphycene analogues incorporating thiazole

The syntheses of the first examples of aromatic thiazole-containing porphycene analogues 3 have been accomplished by oxidation of the corresponding 3,20:10,13-diepithio-6,9:16,19-diimino-1,11-diaza[20]annulenes 9 with DDQ. Compounds 9a-c have been synthesized by McMurry coupling reaction of the diformylated 2-(1H-pyrrol-2-yl)thiazoles 8a-c, readily available by a three-step reaction sequence using 2-pyrrolethiocarboxamide (4) as starting material. The aromaticity of the 21,23-dithia-3,13-diazaporphycenes 3 is clearly established by NMR and UV/Vis spectroscopy and verified by X-ray crystal structure analysis of 3b.