145758-41-4Relevant academic research and scientific papers
Reactivity and π-facial selectivity of nucleophile addition to the radical cations of 7-benzhydrylidenenorbornene derivatives
Ishii, Hideki,Shiina, Satoshi,Hirano, Takashi,Niwa, Haruki,Ohashi, Mamoru
, p. 523 - 526 (1999)
For correlating a homoconjugation structure of a radical cation to its reactivity with a nucleophile, the reactivity and π-facial selectivity of CH3OH and H2O addition to the radical cations of 7- benzhydrylidenenorbornene derivative
Photoinduced Electron-transfer Reaction of 7-Benzhydrylidenenorbornene: Chemical Capture of a Radical Cation Intermediate with Nonclassical Cation Character
Hirano, Takashi,Shiina, Satoshi,Ohashi, Mamoru
, p. 1544 - 1545 (2007/10/02)
A photoinduced electron-transfer reaction of benzhydrylidenenorbornene 1 as an electron donor gives the radical cation, which could be captured chemically by methanol or by the intramolecular hydroxy group, indicating the existence of a strong homoconjugative interaction between the exocyclic double bond and the C(2)-C(3) double bond.
