145828-13-3

Basic information

• Product Name: α-D-1,3,5-tri-O-benzoyl-2-O-[3-(trifluoromethyl)benzoyl]ribofuranose
• Synonyms: α-D-1,3,5-tri-O-benzoyl-2-O-[3-(trifluoromethyl)benzoyl]ribofuranose
• CAS NO: 145828-13-3
• Molecular Weight: 634.562
• Mol File: 145828-13-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: α-D-1,3,5-tri-O-benzoyl-2-O-[3-(trifluoromethyl)benzoyl]ribofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: α-D-1,3,5-tri-O-benzoyl-2-O-[3-(trifluoromethyl)benzoyl]ribofuranose(145828-13-3)
• EPA Substance Registry System: α-D-1,3,5-tri-O-benzoyl-2-O-[3-(trifluoromethyl)benzoyl]ribofuranose(145828-13-3)

Safety Data

• Hazardous Substances Data: 145828-13-3(Hazardous Substances Data)

Upstream product

• 2251-65-2 3-(Trifluoromethyl)benzoyl chloride 
• 22224-41-5 1,3,5-tri-O-benzoyl-α-D-ribofuranoside 
• 454-92-2 3-(trifluoromethyl)benzoic acid 

Downstream Products

• 145828-14-4 3,5-di-O-benzoyl-2-O-(3-(trifluoromethyl)benzoyl)-α-D-ribofuranosyl bromide 
• 182004-61-1 3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]-5-trifluoromethyluridine 
• 182004-58-6 3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]uridine 
• 182004-59-7 3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]-5-methyluridine 
• 182004-60-0 3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]-5-fluorouridine 
• 203172-89-8 3-Trifluoromethyl-benzoic acid (2S,3R,4R,5R)-4-benzoyloxy-5-benzoyloxymethyl-2-(diisopropoxy-phosphorylmethoxy)-tetrahydro-furan-3-yl ester 
• 303040-98-4 N²-acetyl-N7-(3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]-β-D-ribofuranosyl)guanine 
• 303041-00-1 N²-acetyl-3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]guanosine 
• 303040-93-9 N⁶-benzoyl-3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]adenosine 
• 303040-78-0 3',5'-di-O-benzoyl-2'-O-[3-(trifluoromethyl)benzoyl]-β-D-ribofuranosylcyanuric acid 
• 1423728-10-2 C₃₃H₂₇F₃N₂O₉ 
• 92758-94-6 C₂₅H₂₄N₂O₇ 
• 148504-69-2 C₂₄H₂₁⁽²⁾HN₂O₇ 
• 15176-29-1 edoxudine 

Relevant articles and documents

Stereocontrolled de novo synthesis of β-2'-deoxyribonucleosides

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Synthesis of 2'-Deoxyribonucleosides: ?-3',5'-Di-O-benzoylthymidine [ Thymidine, 3',5'-dibenzoate ]

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Radical Rearrangement of 2-O-(Diphenylphosphoryl)glycosyl Bromides. A New Synthesis for 2-Deoxy Disaccharides and 2-Deoxy Ribonucleosides

2-Deoxy-1-O-diphenylphosphoryl glycosides react with nucleophiles under mild conditions giving access to 2-deoxy disaccharides and nucleosides.The intermediate 2-deoxy-1-O-diphenylphosphoryl compounds were generated in situ by a radical 2 -> 1 migration of the phosphate ester group.This is the first observation of a rearrangement of a phosphate ester in radicals.ESR experiments and quenching of the radical at C2 by tin hydride or tin deuteride were used to detect the intermediates and to prove their structure.