145850-66-4

Basic information

• Product Name: Benzene, 1,1'-(1-methyl-1,3-propanediyl)bis[3-methyl-
• CAS NO: 145850-66-4
• Molecular Formula: C18H22
• Molecular Weight: 238.373
• Mol File: 145850-66-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-methyl-1,3-propanediyl)bis[3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-methyl-1,3-propanediyl)bis[3-methyl-(145850-66-4)
• EPA Substance Registry System: Benzene, 1,1'-(1-methyl-1,3-propanediyl)bis[3-methyl-(145850-66-4)

Safety Data

• Hazardous Substances Data: 145850-66-4(Hazardous Substances Data)

Upstream product

• 100-80-1 3-methylstyrene 
• 1191-47-5 dibutylmagnesium 
• 4907-44-2 di-n-propylmagnesium 
• 93876-99-4 3,3′-dimethyldypnone 

Relevant articles and documents

CATYLYTIC SYNTHESIS AND REACTIONS OF MAGNESIOCYCLOALKANES. 2. SYNTHESIS OF SUBSTITUTED MAGNESIOCYCLOPENTANES IN THE PRESENCE OF ZYRCONIUM COMPLEXES

Catalytic cyclometallation of styrene, m-methylstyrene, p-tert-butylstyrene, and 1-hexene with di n-alkylmagnesium compounds (n-R2Mg, where R=C3H7, C4H9, C6H13) in the presence of Cp2Zr2Cl2 has been given high yields of 2,4-disubstituted magnesiocyclopentanes.The probable mode of formation of magnesiocyclopentanes, involving zirconocyclopentanes formed from Cp2ZrCl2, n-R2Mg, and the appropiate olefins as reactive intermediates in the cyclometallation, is discussed. Keywords: catalytic synthesis, substituted styrenes, alkenes, magnesium alkyls.