145854-70-2Relevant academic research and scientific papers
A General Route to N(SCl)2+ and SNS+ Salts
Ayres, Bryan,Banister, Arthur J.,Coates, Philip D.,Hansford, Michael I.,Rawson, Jeremy M.,et al.
, p. 3097 - 3104 (2007/10/02)
A 1:3 mixture of (NSCl)3 and AgX (where X is a 'hard' anion) in liquid SO2 act as a convenient soure of X.The reactivity of salts of this SN+ cation towards sulfur and SCl2 has been examined.Reaction of (NSCl)3 with AgX (X = AsF6, SbF6 or C
Cycloaddition reactions of SNSAsF6 with aryl nitriles and diphenylacetylene; the preparation and characterization of aryl 1,3,2,4- and 1,2,3,5-dithiadiazole radicals
Passmore, Jack,Sun, Xiaoping,Parsons, Simon
, p. 2972 - 2979 (2007/10/02)
The SNS+ cation (in SNSAsF6) underwent symmetry-allowed concerted cycloadditions with the aryl nitriles RCN (R = 2,5-Me2C6H3, Ph, p-O2NC6H4, and 3,5-(O2N)2C6H3) and diphenylacetylene.The cycloadducts (R = 2,5-Me2C6H3, Ph, p-O2NC6H4, and 3,5-(O2N
The Kinetics of the Quantitative, Symmetry Allowed, Reverse Electron Demand Cycloadditions of the Pseudo-1,3-Dipole SNS+ with Alkynes and Nitriles; the Preparation and X-Ray Crystal Structures of and : The Precursor to a New Class of S2N2C-CN2S2n+ (n=0,1,2)...
Parsons, Simon,Passmore, Jack,Schriver, Melbourne J.,White, Peter S.
, p. 369 - 371 (2007/10/02)
The rates of cycloaddition reactions of SNSAsF6 with alkynes and nitriles increase as the ionization potential (Ei) of the triple bond decreases, and accordingly reaction with HCCCN occurs preferentially at the CC bond; however, it reacts with NCCN quantitatively to give the dication , from which several members of a new family of S2N2C-CN2S2n+ (n=0,1,2) bicyclics have been prepared.
