145872-72-6Relevant academic research and scientific papers
The epoxy-Ramberg-Baecklund reaction (ERBR): A sulfone-based method for the synthesis of allylic alcohols
Evans, Paul,Johnson, Paul,Taylor, Richard J. K.
, p. 1740 - 1754 (2007/10/03)
The epoxy-Ramberg-Baecklund reaction (ERBR) is outlined, in which α,β-epoxy sulfones are converted into a range of mono-, di- and tri-substituted allylic alcohols, on treatment with base. Modification of this method enabled the preparation of enantio-enriched allylic alcohols following the diastereoselective epoxidation of enantio-enriched vinyl sulfones that were accessed efficiently from the chiral pool. The scope, optimisation and limitations of the ERBR as a method for the preparation of allylic alcohols are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
NOUVEAUX DECONTAMINANTES. DESTRUCTION OXYDATIVE D'UN SILIMI DE L'YPERITE: LE PHENYL-2 CHLORO-2' DIETHYLSULFURE PAR LE MONOPERSULFATE DE POTASSIUM
Leblanc, Andre,Fosset, Laurent,Magnaud, Gilbert,Delmas, Gerard,Desgranges, Michel,et al.
, p. 141 - 146 (2007/10/02)
The reaction of potassium monopersulfate (CUROX or OXONE) with 2-phenyl 2'-chloro diethylsulfide PhCH2CH2SCH2CH2Cl goes to completion in a very short time.The intermediate chlorinated sulfone PhCH2CH2SO2CH2CH2Cl leads to the phenethylvinylsulfone PhCH2CH2SO2CH=CH2 by HCl elimination. Key words: decontamination; potassium monopersulfate; yperite.
