145874-04-0Relevant articles and documents
Palladium-catalyzed norbornene-carbon monoxide co-oligomerization initiated by aryl groups and terminated by double bond formation
Dalcanale, E.,An, Z.,Battaglia, L. P.,Catellani, M.,Chiusoli, G. P.
, p. 375 - 388 (1992)
The use of m-iodophenol as initiator in palladium-catalyzed norbornene-carbon monoxide oligomerization in the presence of potassium acetate unexpectedly leads to termination by double bond formation in spite of the limitations to β-H-anti elimination.The presence of endo products points to preliminary exo-to-endo isomerization through enolization.The X-ray structure of one stereoisomer (Ia) is given.