145874-04-0

Basic information

• Product Name: Bicyclo[2.2.1]hept-2-en-2-yl-[(1S,2R,3S,4R)-3-(3-hydroxy-phenyl)-bicyclo[2.2.1]hept-2-yl]-methanone
• CAS NO: 145874-04-0
• Molecular Weight: 308.42
• Mol File: 145874-04-0.mol

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]hept-2-en-2-yl-[(1S,2R,3S,4R)-3-(3-hydroxy-phenyl)-bicyclo[2.2.1]hept-2-yl]-methanone(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]hept-2-en-2-yl-[(1S,2R,3S,4R)-3-(3-hydroxy-phenyl)-bicyclo[2.2.1]hept-2-yl]-methanone(145874-04-0)
• EPA Substance Registry System: Bicyclo[2.2.1]hept-2-en-2-yl-[(1S,2R,3S,4R)-3-(3-hydroxy-phenyl)-bicyclo[2.2.1]hept-2-yl]-methanone(145874-04-0)

Safety Data

• Hazardous Substances Data: 145874-04-0(Hazardous Substances Data)

Upstream product

• 498-66-8 norborn-2-ene 
• 201230-82-2 carbon monoxide 
• 626-02-8 3-Iodophenol 

Relevant articles and documents

Palladium-catalyzed norbornene-carbon monoxide co-oligomerization initiated by aryl groups and terminated by double bond formation

The use of m-iodophenol as initiator in palladium-catalyzed norbornene-carbon monoxide oligomerization in the presence of potassium acetate unexpectedly leads to termination by double bond formation in spite of the limitations to β-H-anti elimination.The presence of endo products points to preliminary exo-to-endo isomerization through enolization.The X-ray structure of one stereoisomer (Ia) is given.