145886-78-8Relevant articles and documents
DICHLORONITROACETIC ACID DERIVATIVES AS ACYLATING AGENTS FOR PRIMARY AMINES, AMMONIA, AND PHENYLHYDRAZINE
Yurtanov, A. I.,Adkhamova, Z. M.,Baidildaeva, S. K.
, p. 891 - 894 (1992)
The corresponding carbamic acid derivatives were obtained (28-91percent) yields) as a result of the reaction of dichloronitroacetic acid derivatives, O2NCCl2COR, (1a-c, R=OEt, OCH2Ph, NH2) with ammonia, methylamine, benzylamine, glycine, phenylhydrazine, and aniline. The probable mechanism of the process and factors that affect the nature of the departing group were discussed. Keywords: dichloronitroacetic acid derivatives, aminolysis, intermediate states, mechanisms of reactions.